Formation of persistent contact ion pairs in solid argon

Authors
Godicke, B Langenscheidt, A Meyer, H Schweig, A
Citation
B. Godicke et al., Formation of persistent contact ion pairs in solid argon, CHEM P LETT, 318(1-3), 2000, pp. 102-106
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
318
Issue
1-3
Year of publication
2000
Pages
102 - 106
Database
ISI
SICI code
0009-2614(20000218)318:1-3<102:FOPCIP>2.0.ZU;2-6
Abstract
Persistent contact ion pairs (CIPs) have been obtained by one-photon-induce d electron transfer from N,N,N',N'-tetramethyl-p-phenylenediamine (TMPD) to tetrachloromethane (CCl4) in solid argon, in addition to TMPD.* free radic al cations (FRCs) generated by two-photon ionization of TMPD as the primary process. The first UV/VIS absorption band of the CIPs is tentatively expla ined on the basis of the corresponding band of the FRCs. (C) 2000 Elsevier Science B.V. All rights reserved.