A dioxin mass balance in an Spanish municipal waste incinerator (MWI) is pr
esented. Input and output inventories from two sampling Collection episodes
including the analysis of PCDD/PCDF in urban solid waste (USW), stack gas
emissions, fly ash and slag are reported. In one collection the levels of U
SW were around 8 pg I-TEQ/g and non-thermal destruction was observed overal
l. In the other collection the levels of USW were higher (around 64 pg I-TE
Q/g) and the dioxin balance revealed a thermal destruction. Analysis of the
different waste materials (textile, organic, plastic, wood and paper) was
performed separately and the textile samples presented the highest levels.
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