A number of technologies, including electrophotographic printing, require a
n understanding of particle-surface adhesion forces. At Xerox, we have deve
loped and applied new techniques in order to understand the dependence of p
article adhesion on physical properties, such as particle charge, shape and
surface roughness. Atomic force microscopy and computer modeling were used
to investigate the effects of surface roughness, external additives and ap
plied electric fields on the adhesion of single particles. Centrifugal deta
chment was used to measure the adhesion force distribution of several hundr
ed particles simultaneously and to determine its sensitivity to particle ch
arge and size. Electric field detachment has enabled rapid characterization
s of the adhesion of particle layers, providing insight into the roles of p
article-surface contact area and nonuniform particle charging on the adhesi
on of ensembles of particles. The addition of digital photography to the de
tachment techniques has allowed in-situ visualization of particle detachmen
t, enabling us to probe interparticle effects on adhesion. (C) 2000 Elsevie
r Science B.V. All rights reserved.