One-step synthesis of disaccharide mimetics via tandem rearrangement of unsaturated disaccharides

Authors
Pearce, AJ Mallet, JM Sinay, P
Citation
Aj. Pearce et al., One-step synthesis of disaccharide mimetics via tandem rearrangement of unsaturated disaccharides, HETEROCYCLE, 52(2), 2000, pp. 819-826
Citations number
7
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
HETEROCYCLES
ISSN journal
03855414 → ACNP
Volume
52
Issue
2
Year of publication
2000
Pages
819 - 826
Database
ISI
SICI code
0385-5414(20000201)52:2<819:OSODMV>2.0.ZU;2-4
Abstract
The unsaturated thioglycoside disaccharide (4) undergoes stereoselective ta ndem reductive rearrangement with TIBAL (triisobutylaluminium) to afford th e (1-->4) ether-linked disaccharide mimetics (1-3).