Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO. Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2

Authors
Lorkovic, IM Ford, PC
Citation
Im. Lorkovic et Pc. Ford, Reactivity of the iron porphyrin Fe(TPP)(NO) with excess NO. Formation of Fe(TPP)(NO)(NO2) occurs via reaction with trace NO2, INORG CHEM, 39(4), 2000, pp. 632
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
4
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000221)39:4<632:ROTIPF>2.0.ZU;2-J
Abstract
Fe(TPP)(NO) (TPP = tetraphenylporphyrinato dianion) does not react observab ly with excess NO in organic solvents at ambient pressure and temperature; however, adventitious NO2 rapidly leads to the nitrosyl nitro product Fe(TP P)(NO)(NO2), which is labile toward loss of Nd. [GRAPHICS]