Iron versus ruthenium oxidation in 1,1 '-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes: EPR and spectroelectrochemical evidence

Authors
Sixt, T Fiedler, J Kaim, W
Citation
T. Sixt et al., Iron versus ruthenium oxidation in 1,1 '-bis(diphenylphosphino)ferrocene-ruthenium(II) complexes: EPR and spectroelectrochemical evidence, INORG CH C, 3(2), 2000, pp. 80-82
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
3
Issue
2
Year of publication
2000
Pages
80 - 82
Database
ISI
SICI code
1387-7003(200002)3:2<80:IVROI1>2.0.ZU;2-G
Abstract
Oxidation of [Cp*RuH(dppf)] (1), dppf = 1,1'-bis(diphenylphosphino)ferrocen e, and [(Cym)RuCl(dppf)](PF6) (2), Cym = p-cymene, occurs at ruthenium for 1 but yields a ferrocenium species for compound 2. (C) 2000 Elsevier Scienc e S.A. All rights reserved.