Informational-statistical thermodynamics of a complex system

Citation
Af. Fonseca et al., Informational-statistical thermodynamics of a complex system, J CHEM PHYS, 112(9), 2000, pp. 3967-3979
Citations number
58
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
112
Issue
9
Year of publication
2000
Pages
3967 - 3979
Database
ISI
SICI code
0021-9606(20000301)112:9<3967:ITOACS>2.0.ZU;2-1
Abstract
We apply a statistical-thermodynamic approach to the study of a particular physical system (two sets of nonlinearly coupled oscillators), driven far a way from equilibrium. Such a system displays a kind of complex behavior con sisting in the so-called Frohlich effect leading in steady-state conditions to a nonequilibrium phase condensation resembling the Bose-Einstein conden sation of systems in equilibrium. A kind of "two-fluid model" arises: the " normal nonequilibrium phase" and Frohlich condensate or "nonequilibrium sup erphase," which is shown to be an attractor of the system. We work out some aspects of the irreversible thermodynamics of this dissipative complex sys tem. Particular nonlinear properties are discussed and Lyapunov exponents d etermined. This kind of system gives a good modeling of polar vibration mod es in polymers and biopolymers. (C) 2000 American Institute of Physics. [S0 021-9606(00)50808-3].