Neutron diffraction (ND) measurements on liquid methanol (CD3OD,CD3O(H/D),C
D3OH) under ambient conditions have been performed to obtain the total (int
ra-+intermolecular), G(dist)(r) and intermolecular, G(inter)(r) radial dist
ribution functions (rdfs) for the three samples. The extent to which interm
olecular structure is affected by using two different intramolecular models
is discussed. The H/D substitution on hydroxyl-hydrogen (Ho) has been used
to extract the partial distribution functions, G(XHo)(dist/inter)(r) (X=C,
O, and H-a methyl hydrogen) and G(XX)(dist/inter)(r) from the difference t
echniques of ND at both the distinct and intermolecular levels. The O-Ho bo
nd length, which has been the subject of controversy in the past, is found
purely from the partial distribution function, G(XHo)(dist)(r) to be 0.98 /- 0.01 Angstrom. The C-H distance obtained from the G(XX)(dist)(r) partial
is 1.08 +/- 0.01 Angstrom. These distances determined by fitting an intram
olecular model to the total distinct structure functions are 0.961 +/- 0.00
1 Angstrom and 1.096 +/- 0.001 Angstrom, respectively. The G(XX)(inter)(r)
function, dominated by contributions from the methyl groups, apart from sho
wing broad oscillations extending up to similar to 14 Angstrom is featurele
ss, mainly because of cancellation effects from six contributing pairs. The
Ho ... Ho partial pair distribution function (pdf), g(HoHo)(r), also deter
mined from the second-order difference, shows that only one other Ho atom c
an be found within a mean Ho ... Ho separation of 2.36 Angstrom. The averag
e position of the O ... Ho hydrogen bond determined purely from experimenta
l G(XHo)(inter)(r) partial distribution function, at 1.75 +/- 0.03 Angstrom
is found to lie in the range (1.75-1.95 Angstrom) of values reported from
computer simulation results. (C) 2000 American Institute of Physics. [S0021
-9606(00)51309-9].