Speed of sound and isentropic compressibility of (1-butanol plus n-hexane plus 1-chlorobutane) and the constituent binary mixtures at the temperatures 298.15 K and 313.15 K

Citation
M. Dominguez et al., Speed of sound and isentropic compressibility of (1-butanol plus n-hexane plus 1-chlorobutane) and the constituent binary mixtures at the temperatures 298.15 K and 313.15 K, J CHEM THER, 32(2), 2000, pp. 155-173
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL THERMODYNAMICS
ISSN journal
00219614 → ACNP
Volume
32
Issue
2
Year of publication
2000
Pages
155 - 173
Database
ISI
SICI code
0021-9614(200002)32:2<155:SOSAIC>2.0.ZU;2-P
Abstract
Densities rho and speeds of sound u for {x(1)C(4)H(10)O + x(2)C(6)H(14) + ( 1 - x(1) - x(2))C4H9Cl} at T = 298.15 K and T = 313.15 K, and the constitue nt binary mixtures {xC(6)H(14) + (1 - x)C4H9Cl} at T = 298.15 K and {xC(4)H (10)O + (1 - x)C6H14}, {xC(4)H(10)O + (1 - x)C4H9Cl}, and {xC(6)H(14) + (1 - x)C4H9Cl} at T = 313.15 K have been measured. The isentropic compressibil ities kappa(S) the excess isentropic compressibilities kappa(S)(E), and the speeds of sound deviations Delta u have been calculated for both the binar y and the ternary systems, from the experimental data. The isentropic compr essibilities have been compared with calculated values from the free length theory (FLT) and collision factor theory (CFT). (C) 2000 Academic Press.