A. Kilian et al., Birefringence free planar optical waveguide made by flame hydrolysis deposition (FHD) through tailoring of the overcladding, J LIGHTW T, 18(2), 2000, pp. 193-198
Stresses developing in a planar waveguide resulting from the different ther
mal expansion coefficients of the substrate and the three glass layers (buf
fer, core and cladding) were analyzed using a finite element method. It can
be shown that mainly the thermal expansion of the overcladding determines
the birefringence in the finished waveguide, Based on that result, recipes
for an overcladding made with the flame-hydrolysis-deposition-(FHD)-process
were devised. We demonstrate the absence of birefringence in a commercial
waveguide layer overclad with this glass, The high doping levels required f
or the cladding to have a thermal expansion coefficient sufficient for this
raises concerns about the moisture sensitivity of such a glass. We examine
d the depth dependent composition of the glass using WD-ESCA (wavelength di
spersive electron microprobe) and show, that at the surface a layer deplete
d of dopants is formed during the high temperature sintering process. This
layer can serve as a protective coating to isolate the underlying, higher d
oped layer from the effects of moisture. Analysis of the stresses shows tha
t this does not effect the birefringence behavior of the waveguide.