Terahertz rotational spectra of NH2OH in the ground and some low excited vibrational states

Authors
Morino, I Yamada, KMT Klein, H Belov, SP Winnewisser, G Bocquet, R Wlodarczak, G Lodyga, W Kreglewski, M
Citation
I. Morino et al., Terahertz rotational spectra of NH2OH in the ground and some low excited vibrational states, J MOL STRUC, 517, 2000, pp. 367-373
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR STRUCTURE
ISSN journal
00222860 → ACNP
Volume
517
Year of publication
2000
Pages
367 - 373
Database
ISI
SICI code
0022-2860(20000216)517:<367:TRSONI>2.0.ZU;2-E
Abstract
The rotational spectra of hydroxylamine, NH2OH, have been measured for the ground and some excited vibrational states, with high precision in the mmW (millimeter wave) and sub-mmW region, up to 1.8 THz, using BWO based spectr ometers and a laser-side-band FIR spectrometer, No tunnel splitting has bee n observed and it is concluded that the barrier to the tunneling motion is very high. The observed line positions have been analyzed with Watson's S-r educed Hamiltonian with extension to higher order terms up to J(10) order. (C) 2000 Elsevier Science B.V. All rights reserved.