A recent paper by Meszena and Westerhoff (1999 J. Phys. A: Math. Gen. 32 30
1) has aimed to address what is referred to as a principal question of biol
ogical thermodynamics, the possibility of describing photosynthesis in term
s of non-equilibrium thermodynamics. The issue is associated with a misrepr
esentation of the fundamental photophysics involved, and as a result the an
alysis is invalid.