We have measured the electron momentum density in both insulating PrBa2Cu3O
7-delta and superconducting YBa2Cu3O7-delta. We find a remarkable differenc
e in the anisotropy of the momentum density, even though LDA based calculat
ions predict similar behaviour for both. Our results can be explained assum
ing Pr on Ba-site substitution disorder and we propose that this phenomenon
is responsible for the observed effects. (C) 2000 Elsevier Science Ltd. Al
l rights reserved.