Spectra from the Rydberg series 1s-np for the principal quantum numbers n g
reater than or equal to 8 of Cl16+ are observed on the JET tokamak. Individ
ual lines up to n = 15 are resolved. The line intensity of n = 10 is enhanc
ed, relative to the underlying 1/n(3) scaling, due to charge exchange colli
sions with neutral deuterium in the ground state. The observations are comp
ared with predictions based on available partial charge exchange cross sect
ion data. There is generally good agreement, however, some details of the p
redicted n-shell distribution are different from those observed in the expe
riment.