Nuclear quadrupole resonance results on the inorganic spin-Peierls compound
CuGeO3 were re-examined using a single crystal and enhanced resolution. A
clear splitting of (CU)-C-63,65 NQR lines of about 250 kHz at 4.2 K was obs
erved. Such a splitting has not been previously seen in Cu NQR spectra meas
ured on polycrystalline samples of CuGeO3 (Itoh M et al 1995 Phys. Rev. B 5
2 3410, Kikuchi et al 1994 J. Phys. Sec. Japan 63 872). The mean frequency
of the Cu doublet is in agreement with the Cu NQR frequency observed on pow
der samples. The splitting does nor disappear with increasing temperature a
bove T-sP exhibiting only a slight kink at around 16 K. This points to a no
n-magnetic origin of the splitting which can be attributed to existence of
at least two non-equivalent Cu crystal sites in CuGeO3 structure, as predic
ted by precise x-ray study and EPR measurements (Hidaka M et al 1997 J. Phy
s.: Condens. Matter 9 809, Yamada I er al 1996 J. Phys.: Condens. Matter 8
2625).