The correct diagnosis of boron deficiency is not yet completely resolved fo
r species where boron is phloem immobile. As some deficiency reactions in t
he extension zone of young roots cannot be reversed after only one hour of
deficiency, boron should be supplied continuously. Several early deficiency
reactions are shown to be related to the concentration of "free" boron. It
is suggested that there is a "minimum" or "critical level" of soluble boro
n (i.e. not tightly bound to rhamno-galacturonan LI) which is needed in the
most boron requiring tissues to avoid deficiency reactions. Determination
of this "soluble" or "exchangeable" boron fraction might improve the diagno
sis of boron deficiency.