Dy. Peng et al., Excess enthalpies of 2,2-dimethylbutane plus cyclohexane plus (octane or dodecane) at 25 degrees C, J SOL CHEM, 29(2), 2000, pp. 153-164
Measurements of excess molar enthalpies at 25 degrees C in a flow microcalo
rimeter, are reported for the two ternary mixtures 2,2-dimethylbutane + cyc
lohexane + n-octane and 2,2-dimethylbutane + cyclohexane + n-dodecane. Smoo
th representations of the results are described and used to construct const
ant enthalpy contours on Roozeboom diagrams. It is shown that useful estima
tes of the ternary enthalpies can be obtained from the Flory theory using o
nly the physical properties of the components and their binary mixtures.