Synthesis and structure of the (tetrahydroxy)oligosiloxane [((BuO)-Bu-t)(3)SiOSi(OH)(2)](2)O

Authors
Rulkens, R Coles, MP Tilley, TD
Citation
R. Rulkens et al., Synthesis and structure of the (tetrahydroxy)oligosiloxane [((BuO)-Bu-t)(3)SiOSi(OH)(2)](2)O, J CHEM S DA, (5), 2000, pp. 627-628
Citations number
40
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
5
Year of publication
2000
Pages
627 - 628
Database
ISI
SICI code
0300-9246(2000):5<627:SASOT(>2.0.ZU;2-L
Abstract
The solid-state structure of the (tetrahydroxy)oligosiloxane [((BuO)-Bu-t)( 3)SiOSi(OH)(2)](2)O, synthesized by the hydrolysis of ((BuO)-Bu-t)(3)SiOSiC l3, reveals molecules composed of four vertex-linked SiO4 tetrahedra and co ntaining four SiOH groups involved in both intermolecular and intramolecula r hydrogen-bonding.