Syntheses and structures of novel heterobimetallic Cu(II)-Au(I) complexes Cu(cyclen)[Au(CN)(2)](2) and Cu(pyz)[Au(CN)(2)](2)

Authors
Yeung, WF Wong, WT Zuo, JL Lau, TC
Citation
Wf. Yeung et al., Syntheses and structures of novel heterobimetallic Cu(II)-Au(I) complexes Cu(cyclen)[Au(CN)(2)](2) and Cu(pyz)[Au(CN)(2)](2), J CHEM S DA, (5), 2000, pp. 629-631
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
5
Year of publication
2000
Pages
629 - 631
Database
ISI
SICI code
0300-9246(2000):5<629:SASONH>2.0.ZU;2-8
Abstract
Two novel cyano Cu-II-Au-I bimetallic complexes, Cu(cyclen)[Au(CN)(2)](2) 1 (cyclen = 1,4,7,10-tetraazacyclododecane) and Cu(pyz)[Au(CN)(2)](2) 2 (pyz = pyrazine) were prepared; 1 has a dimeric structure arising from Au-I... Au-I interactions, while 2 consists of linear pyrazine-bridged copper chain s intercalated to produce a 2-D pleated sheet structure.