Polarized infrared study of a polymer network deformation in a nematic liquid crystal host

Citation
Cd. Hoke et al., Polarized infrared study of a polymer network deformation in a nematic liquid crystal host, LIQ CRYST, 27(3), 2000, pp. 359-363
Citations number
19
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LIQUID CRYSTALS
ISSN journal
02678292 → ACNP
Volume
27
Issue
3
Year of publication
2000
Pages
359 - 363
Database
ISI
SICI code
0267-8292(200003)27:3<359:PISOAP>2.0.ZU;2-T
Abstract
Using polarized infrared (IR) spectroscopy we have observed deformation of a polymer network in a liquid crystal host during the reorientation of the liquid crystal by an external electric field. In the system studied, contai ning 2% BMBB-6 polymerized at zero applied field in the host nematic liquid crystal 6CB, the observed deformation angle was between 20 degrees and 40 degrees+/-10 degrees. These experimental results provide some of the first conclusive experimental evidence that the polymer network elastically defor ms as a direct result of the reorientation of the liquid crystal host.