NMR study of the low-temperature phase of vanadium dioxide

Authors
Boyarskii, LA Gabuda, SP Kozlova, SG
Citation
La. Boyarskii et al., NMR study of the low-temperature phase of vanadium dioxide, LOW TEMP PH, 26(2), 2000, pp. 147-151
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
LOW TEMPERATURE PHYSICS
ISSN journal
1063777X → ACNP
Volume
26
Issue
2
Year of publication
2000
Pages
147 - 151
Database
ISI
SICI code
1063-777X(200002)26:2<147:NSOTLP>2.0.ZU;2-I
Abstract
The magnetic shielding and quadrupole interaction constants of V-51 nuclei in the low-temperature (nonconducting) phase of vanadium dioxide are determ ined by magnetic resonance on the (51V) nuclei. It is shown that the metal- insulator transition in VO2 is accompanied by a change in the sign of the m agnetic shielding constant and by an electronic transition 2V(4+)--> V3++V5 +, which is accompanied by a charge ordering in the cation sublattice. (C) 2000 American Institute of Physics. [S1063-777X(00)01102-6].