The influence of an oxygen impurity on the efficiency of desorption of exci
ted atoms and molecules from the surface of crystalline argon is investigat
ed. A significant increase in the yield of desorbed particles is observed a
t an O-2 concentration of 1 at. % in the argon host matrix. It is shown tha
t a xenon impurity does not have a similar effect. Possible mechanisms are
proposed for the stimulation of argon desorption by impurity oxygen. One of
them may involve the formation of argon microclusters around O- ions near
the surface of the crystal. Another mechanism may be due to an increase in
the probability of recombination of Ar-2(+) with an electron on account of
the hopping of the negative charge between the O-2(-) and Ar-2(+) ions. (C)
2000 American Institute of Physics. [S1063-777X(00)01202-0].