Characterization of the dynamic properties of binary polypropylene blends via the hysteresis measurement method

Citation
F. Raue et Gw. Ehrenstein, Characterization of the dynamic properties of binary polypropylene blends via the hysteresis measurement method, MACRO SYMP, 148, 1999, pp. 229-240
Citations number
5
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR SYMPOSIA
ISSN journal
10221360 → ACNP
Volume
148
Year of publication
1999
Pages
229 - 240
Database
ISI
SICI code
1022-1360(199912)148:<229:COTDPO>2.0.ZU;2-W
Abstract
Due to the poor impact behavior of polypropylene (PP) at low temperatures, blending PP with an elastomeric phase is a common way to improve some of th e characteristic quantities. The property profile of thermoplastic elastome rs strongly depends on the content of the elastomeric component. For applic ations under dynamic loading conditions, the corresponding material behavio r is of importance. In order to reduce long testing times with constant amp litude loading, the hysteresis measurement method, which evaluates the hyst eresis loop and makes use of a stepwise load increase procedure (SLIP), was developed. Binary blends based on PP were compounded with either ethylene- propylene-dien-rubber (EPDM), metallocene polymerized polyethylene (mPE), o r styrene-ethylene-butylene-styrene block copolymer (SEBS) as the elastomer ic phase. Static and dynamic tests under tensile and pressure conditions we re performed in order to evaluate the influence of the type of elastomeric phase on the properties of these blends. It is shown how the hysteresis mea surement method can be used to determine dynamic load limits for the applic ation of these blends and of other polymers. Some properties improved sligh tly when using mPE.