Poly(methylphenylsilane) plasma polymer layers of the thickness ranging fro
m 10(-2) to 10(0) mu m intended to engineer interphases in glass fibre rein
forced polymer composites and light-emitting displays were prepared by r.f.
glow discharge technique. The films synthesized fi om a mixture of dichlor
o(methyl)phenylsilane vapor and gaseous hydrogen were deposited on flat gla
ss and silicon substrates and glass fibres as well. Deposition conditions w
ere optimized to obtain required thickness, mechanical and electrical prope
rties of interphases. Prepared layers were amorphous, relatively rigid and
transparent at room temperature with excellent adhesion to substrates. The
surface of plasma polymer is rough with isolated (silicon substrate) and co
nglomerate (glass substrate) grains. FTIR and XPS spectra revealed a great
amount of atomic oxygen bound to silicon atoms and enabled to determine the
atomic concentrations. The structure model is proposed assuming a carbosil
oxane network with not-crosslinked methyl and phenyl groups.