Vm. Vaubert et al., Development of slurry-based Ca0.5Sr0.5Zr4(PO4)(6) (CS-50) coatings for SiCin fossil energy applications, MATER HIGH, 16(4), 1999, pp. 175-180
Coatings of Ca,,Sr,,Zr,(PO,), (CS-50), an ultra-low thermal-expansion mater
ial, have been successfully developed to protect SiC-based materials from s
ulfate salt corrosion. The coatings were applied to fiber-reinforced, SiC-m
atrix composite heat exchanger tubes and clay-bonded SIG. Aqueous slurries
were prepared and applied to the SiC substrates. One coating process for he
at exchanger material substrates, consisted of mechanically dipping the sam
ples in a slip. A spin-coating process has also been developed that produce
d thin, non-obstructing coatings for hot-gas filter substrates. The thermal
shock and corrosion resistance of coated parts were evaluated, and prelimi
nary results are encouraging for the use of CS-50 as a protective coating.