Sz. Tokmoldin et al., Comparison of electronic structure and properties of hydrogen-associated and thermal double donors in silicon, MAT SCI E B, 71, 2000, pp. 263-267
Infrared (IR) and electron paramagnetic resonance (EPR) studies of quenchin
g-dependent hydrogen-related double donor (HDD) formed in proton-implanted
n-Si and p-Si upon annealing above 300 degrees C were carried out. IR data
taken at liquid He and N-2 reveal that quenching-dependent IR absorption li
nes is due to HDD electronic excitations. An analysis of Si-H local vibrati
onal modes and EPR data on AA1 EPR center allow to conclude that HDD is an
interstitial-type complex with C-2v-symmetry. There are similarities in str
uctures and properties of HDD and thermal double donors (TDD). However, uni
axial stress-induced alignment and recovery kinetics of HDD (AA1 EPR center
) show strong difference in comparison with TDD (NL8 EPR center). (C) 2000
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