Dimerization of cyclopentadienyl ligands in the synthesis of transition metal complexes. 1,4,5,6,7,10,11,12-octamethyltricyclo[7.3.0.0(3,7)]-dodeca-3,5,9,11-tetraene and the complex of 1,1 ',3,3 '-tetrakis-(tert-butyl)-1,1 '-dihydrofulvalene with I-3(-)

Authors
Belsky, VK Khvostov, AV Gun'ko, YK Bulychev, BM Knyazhanskii, SY
Citation
Vk. Belsky et al., Dimerization of cyclopentadienyl ligands in the synthesis of transition metal complexes. 1,4,5,6,7,10,11,12-octamethyltricyclo[7.3.0.0(3,7)]-dodeca-3,5,9,11-tetraene and the complex of 1,1 ',3,3 '-tetrakis-(tert-butyl)-1,1 '-dihydrofulvalene with I-3(-), RUSS CHEM B, 48(12), 1999, pp. 2285-2289
Citations number
48
Categorie Soggetti
Chemistry
Journal title
RUSSIAN CHEMICAL BULLETIN
ISSN journal
10665285 → ACNP
Volume
48
Issue
12
Year of publication
1999
Pages
2285 - 2289
Database
ISI
SICI code
1066-5285(199912)48:12<2285:DOCLIT>2.0.ZU;2-#
Abstract
1,4,5,6,7,10,11,12-Octamethyltricyclo[7.3.0.0(3,7)]dodeca-3,5,9,11-tetraene was obtained as a by-product in the synthesis of (C5Me5)(2)CeCl from CeCl3 and NaC5Me5. The complex of 1,1',3,3'-tetrakis(tert-butyl)-1,1'-dihydroful valene with I-3(-) was obtained as the major product in the reaction of YbI 3 with 1,3-(Bu2C5H3Na)-C-t. The structures of the title compounds were esta blished by X-ray diffraction analysis.