A bulk nanocrystalline (nc) pure copper with high purity and high density w
as synthesized by electrodeposition, An extreme extensibility (elongation e
xceeds 5000%) without a strain hardening effect was observed when the ne co
pper specimen was rolled at room temperature. Microstructure analysis sugge
sts that the superplastic extensibility of the ne copper originates from a
deformation mechanism dominated by grain boundary activities rather than La
ttice dislocation, which is also supported by tensile creep studies at room
temperature. This behavior demonstrates new possibilities for scientific a
nd technological advancements with ne materials.