Preferential flow through intact soil cores: Effects of matric head

Continuous soil pores may act as pathways for preferential flow depending o n their size and water status (filled or drained), the latter being largely controlled by the soil matric head (h). The literature contains a,ride ran ge of proposed minimal pore sizes that may contribute to preferential now. The objective of this study was to examine the relationship between h (and corresponding pore sizes) and preferential solute transport in a naturally structured soil. Tracer ((H2O)-H-3 and pentafluorobenzoic acid, [PFBA]) mis cible displacement experiments were performed at several h values in intact soil cores (15-cm diameter, 30-cm length) using an apparatus especially su ited to maintain constant h while collecting large effluent volumes, To tes t for the occurrence of preferential now, observed breakthrough curves (BTC s) were evaluated for physical nonequilibrium (PNE) using a comparison betw een fitted local equilibrium (LE) and PNE models. Fitting results of the ob served BTCs indicated absence of PNE in all solute transport experiments at h less than or equal to -10 cm, Experiments at h greater than or equal to -5 cm consistently exhibited PNE conditions, indicating the presence of pre ferential flow. These results suggest that soil pores with effective radii of 150 mu m and smaller (water-filled at h = -10 cm) do not contribute to p referential flow. Observed pore water velocities were not indicative of the presence or absence of preferential flow conditions. Continuous measuremen ts of soil water content (theta) using time domain reflectometry (TDR) reve aled that at h = -10 cm, ,2% of the soil volume (1-5% of a at saturation) h ad drained.