Raman spectra of KNbO3 under high pressure have been analyzed on the basis
of the two-mode coupling model. It has been found that the phase transition
s from orthorhombic to tetragonal and from tetragonal to cubic occur at 7 a
nd 8 GPa, respectively, accompanied by an abrupt jump of the mode width of
one mode. The mode coupling occurs even in the cubic phase. (C) 2000 Elsevi
er Science Ltd. All rights reserved.