Original annulation in anthraquinone series: Synthesis of new 2,3-dialkylnaphthacene-5,12-diones

Authors
Terme, T Crozet, MP Giraud, L Vanelle, P
Citation
T. Terme et al., Original annulation in anthraquinone series: Synthesis of new 2,3-dialkylnaphthacene-5,12-diones, TETRAHEDRON, 56(8), 2000, pp. 1097-1101
Citations number
23
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
8
Year of publication
2000
Pages
1097 - 1101
Database
ISI
SICI code
0040-4020(20000218)56:8<1097:OAIASS>2.0.ZU;2-O
Abstract
2,3-Bis(chloromethyl)-1,4-anthraquinone reacts with primary nitroalkanes in a one-pot synthesis under standard S(RN)1 reaction conditions (inert atmos phere, photostimulation) and in a phase-transfer system to give original 2, 3-dialkylnaphthacene-5,12-diones in fairly good yields. (C) 2000 Elsevier S cience Ltd. All rights reserved.