Dehydrogenative condensation of SiH and SH bonds. A metal-catalyzed protocol to stable thiopolysiloxanes

Authors
Chauhan, BPS Boudjouk, P
Citation
Bps. Chauhan et P. Boudjouk, Dehydrogenative condensation of SiH and SH bonds. A metal-catalyzed protocol to stable thiopolysiloxanes, TETRAHEDR L, 41(8), 2000, pp. 1127-1130
Citations number
17
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
8
Year of publication
2000
Pages
1127 - 1130
Database
ISI
SICI code
0040-4039(20000219)41:8<1127:DCOSAS>2.0.ZU;2-V
Abstract
Dehydrocoupling of polyhydrosiloxanes with thiols proceeded smoothly in the presence of Wilkinson's catalyst to furnish polythioethers in high yields under mild conditions. The process is free of rearrangement and crosslinkin g reactions. (C) 2000 Elsevier Science Ltd. All rights reserved.