Polycrystalline CuIn2Se3.5, CuIn3Se5 and CuIn5Se8 have been synthesized in
vacuum under different cooling conditions resulting in different phases. X-
ray diffraction and Rietveld refinement of the diagrams have been used to c
haracterize the different structures obtained. The two former compounds wer
e refined using two different types of structure: stannite (S.G.: I42m) and
the proposed P-chalcopyrite (S.G.: P42c). The determined bond distances af
ter refinements indicate a higher tetragonal distortion for stannite type s
tructure than P-chalcopyrite structure. These results seem to indicate that
the Cu-In-Se structure with these two stoichiometries belongs to the P42c
S.G. On the other hand, for the CuIn5Se8 compound a far different XRD diagr
am was obtained where all the reflections have been assigned to two structu
res, named gamma-phases. one trigonal (gamma) and one hexagonal (gamma(H)).
(C) 2000 Elsevier Science S.A. All rights reserved.