Electrodeposition of ZnTe for photovoltaic cells

In this paper we report on the electrodeposition process from a highly acid ic aqueous sulphate electrolyte and discuss the relationships between elect rochemical kinetics and crystalline structure of the electrodeposits. The e lectrochemical kinetics were studied by voltammetric and potentiostatic met hods, showing the peculiarities of the cathodic process of highly acidic ba ths, leading - under suitable plating conditions - to the removal of the Te excess which is typical for the ZnTe electrodeposition systems reported in the literature. Potential transient techniques and scanning electron micro scopy (SEM) imaging were used to study the nucleation. They showed that the nucleation process is instantaneous. The crystalline structure of the depo sits was studied by X-ray diffraction (XRD), revealing the possibility of g rowing directly cubic ZnTe films under suitable electrochemical conditions. A minor amount of Te can form at the surface as a result of etching by the electrodeposition bath. Structural data were complemented by X-ray photoel ectron spectroscopy (XPS) analyses and compositional measurements by energy dispersive spectrometry (EDS). (C) 2000 Elsevier Science S.A. All rights r eserved.