Dipotassium dialuminium diantimonate, K-2[Al2Sb2O7], crystallizes in the tr
igonal space group <P(3)over bar m1>. The structure is isotypic with K2Pb2G
e2O7 and consists of [Al2Sb2O7](2-) layers containing Al3+ in a nearly regu
lar tetrahedral and Sb3+ in a Psi-tetrahedral environment of O ligands.