Bis[(mu-cyclopentylamino-N : N)dimethylaluminium(III)]

Authors
Craig, FJ Kennedy, AR Mulvey, RE
Citation
Fj. Craig et al., Bis[(mu-cyclopentylamino-N : N)dimethylaluminium(III)], ACT CRYST C, 56, 2000, pp. 31-32
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
1
Pages
31 - 32
Database
ISI
SICI code
0108-2701(200001)56:<31:B:N>2.0.ZU;2-2
Abstract
Reaction of AlMe3 with NH2(C5H9) caused the evolution of methane and produc ed the dimeric species bis(mu-cyclopentylamino-N:N)bis bis[dimethylaluminiu m(III)], [Al(CH3)(2)(C5H10N)], which was found to adopt a cis configuration of cyclopentyl groups about a bent AlNAlN ring (which has twofold crystall ographic symmetry) instead of the more common trans arrangement.