From the quaternary alkaloidal fraction of the dried tubers of Stephania ce
pharantha, tyro new isoquinoline alkaloids, stecepharine and tetradehydrore
ticuline have been isolated along with the known compounds, magnoflorine, m
enisperine, steponine, cyclanoline. oblongine, cis-N-methylcapaurine and 2'
-N-methylisotetrandrine. cis-N-Methylcapaurine (=9-O-methylstecepharine) wa
s isolated as a natural product for the first time. Their structures were d
etermined on the basis of spectroscopic evidence.