Novel catalytic asymmetric sulfoxidation in water using the hypervalent iodine reagent iodoxybenzene

Authors
Tohma, H Takizawa, S Morioka, H Maegawa, T Kita, Y
Citation
H. Tohma et al., Novel catalytic asymmetric sulfoxidation in water using the hypervalent iodine reagent iodoxybenzene, CHEM PHARM, 48(3), 2000, pp. 445-446
Citations number
20
Categorie Soggetti
Chemistry & Analysis
Journal title
CHEMICAL & PHARMACEUTICAL BULLETIN
ISSN journal
00092363 → ACNP
Volume
48
Issue
3
Year of publication
2000
Pages
445 - 446
Database
ISI
SICI code
0009-2363(200003)48:3<445:NCASIW>2.0.ZU;2-J
Abstract
A new catalytic asymmetric oxidation of sulfides to sulfoxides in water usi ng the hypervalent iodine(V) reagent iodoxybenzene (PhIO2) has been develop ed, This methodology is distinctly different from the previously reported u se of cyclodextrins or biological catalysts and provides a new route to asy mmetric sulfoxidation in water.