Synthesis and properties of alkylperoxocobalt(III) porphyrin and porphycene

Authors
Hayashi, T Okazaki, K Shimakoshi, H Tani, F Naruta, Y Hisaeda, Y
Citation
T. Hayashi et al., Synthesis and properties of alkylperoxocobalt(III) porphyrin and porphycene, CHEM LETT, (2), 2000, pp. 90-91
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
2
Year of publication
2000
Pages
90 - 91
Database
ISI
SICI code
0366-7022(20000205):2<90:SAPOAP>2.0.ZU;2-V
Abstract
Alkylcobalt(III) and alkylperoxocobalt(III) species of porphyrin and porphy cene have been prepared and characterized by UV-vis and H-1 NMR spectroscop ic measurements. Thermal decomposition of the alkylperoxocobalt species pro ceeds via Co-O or O-O bond cleavage, which depends on the coordination of a n axial ligand.