Reduction of molybdenum(V) chloride with various reducing metals: Reactivity correlations with the descendant Lewis acids

Authors
Hara, R Guo, QX Takahashi, T
Citation
R. Hara et al., Reduction of molybdenum(V) chloride with various reducing metals: Reactivity correlations with the descendant Lewis acids, CHEM LETT, (2), 2000, pp. 140-141
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
2
Year of publication
2000
Pages
140 - 141
Database
ISI
SICI code
0366-7022(20000205):2<140:ROMCWV>2.0.ZU;2-G
Abstract
Reactivity of low-valent molybdenum prepared from MoCl5 with various reduci ng metals in DME, was dependent on the reducing metals in the order of Al > Sn, In > Zn, Mg, Li in the case of cyclotrimerization of alkynes. This ord er is par allel to the acidity of the descendant Lewis acids.