Palladium homobimetallic complexes with bridging pi-conjugated ligands

Authors
Moriuchi, T Bandoh, S Kamikawa, M Hirao, T
Citation
T. Moriuchi et al., Palladium homobimetallic complexes with bridging pi-conjugated ligands, CHEM LETT, (2), 2000, pp. 148-149
Citations number
29
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
2
Year of publication
2000
Pages
148 - 149
Database
ISI
SICI code
0366-7022(20000205):2<148:PHCWBP>2.0.ZU;2-K
Abstract
The palladium homobimetallic complexes 2a and 2b with a bridging pi-conjuga ted molecule, N.N'-bis(4'-pyridplmethylidene)-1,4-phenylenediamine (L-2a) a nd 2'-pyridyl derivative L-2b. were respectively synthesized and characteri zed by X-ray crystal structure analysis and cyclic voltammetry. H-1-NMR of 2b indicates the five-coordinate geometry on the palladium center.