Lewis acid catalysis in supercritical carbon dioxide. Use of scandium tris(heptadecafluorooctanesulfonate) as a Lewis acid catalyst in Diels-Alder and aza Diels-Alder reactions

Authors
Matsuo, J Tsuchiya, T Odashima, K Kobayashi, S
Citation
J. Matsuo et al., Lewis acid catalysis in supercritical carbon dioxide. Use of scandium tris(heptadecafluorooctanesulfonate) as a Lewis acid catalyst in Diels-Alder and aza Diels-Alder reactions, CHEM LETT, (2), 2000, pp. 178-179
Citations number
40
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
2
Year of publication
2000
Pages
178 - 179
Database
ISI
SICI code
0366-7022(20000205):2<178:LACISC>2.0.ZU;2-Q
Abstract
Diels-Alder reactions of carbonyl dienophiles with dienes and aza Diels-Ald er reactions of imines with a diene have been successfully carried out usin g scandium tris(heptadecafluorooctanesulfonate) (Sc(OSO2C8F17)(3)) as a Lew is acid catalyst in supercritical carbon dioxide (scCO(2)). It was revealed that the length of perfluorocarbon chains of the scandium catalyst was an essential factor for the catalytic activity in scCO(2).