Low symmetrical phthalocyanines having spectroscopic and electrochemical properties characteristic of unexpected accidental S-1 state degeneracy and non-planar distortions

Authors
Nemykin, VN Kobayashi, N Nonomura, T Luk'yanets, EA
Citation
Vn. Nemykin et al., Low symmetrical phthalocyanines having spectroscopic and electrochemical properties characteristic of unexpected accidental S-1 state degeneracy and non-planar distortions, CHEM LETT, (2), 2000, pp. 184-185
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
2
Year of publication
2000
Pages
184 - 185
Database
ISI
SICI code
0366-7022(20000205):2<184:LSPHSA>2.0.ZU;2-6
Abstract
Low-symmetrical phthalocyanines (Pcs) 2-5 prepared by mixed condensation of tetraphenylphthalonitrile and 4-phenylthiophthalonitrile in the presence o f a copper salt. show spectroscopic, electrochemical, and molecular model i ndications which suggest varying degrees of non-planar distortions of thp P c plane and unexpected S-1 state degeneracy.