Synthesis and characterization of heterodinuclear complexes pentacarbonyl[(dimethylaminomethyl)ferrocene] molybdenum and pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten

Authors
Pavlik, I Pavlista, M Jacob, K Pietzsch, C Lebl, T Vinklarek, J
Citation
I. Pavlik et al., Synthesis and characterization of heterodinuclear complexes pentacarbonyl[(dimethylaminomethyl)ferrocene] molybdenum and pentacarbonyl[(dimethylaminomethyl)ferrocene]tungsten, COLL CZECH, 65(1), 2000, pp. 23-34
Citations number
28
Categorie Soggetti
Chemistry
Journal title
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
ISSN journal
00100765 → ACNP
Volume
65
Issue
1
Year of publication
2000
Pages
23 - 34
Database
ISI
SICI code
0010-0765(200001)65:1<23:SACOHC>2.0.ZU;2-5
Abstract
(Dimethylaminomethyl)ferrocene (HFcR, R = CH2NMe2) reacts with Mo(CO)(6) an d W(CO)(6) under substitution of one CO group and formation of the donor-ac ceptor complexes of the formula HFcRM(CO)(5) (M = Mo, W). These yellow micr ocrystalline derivatives were characterized by mass, UV-VIS, IR, NMR and Mo ssbauer spectroscopy.