Change of Sm-Nd isotope composition during weathering of till

Weathering of till in northern Sweden results in the formation of well-deve loped spodosols. The till is dominated by 1.9-1.8 Ga granitic material. The REE are among the elements most strongly depleted during weathering, and t he loss of REE from the E-horizon decreases as the atomic number increases. To study if weathering leads to a change of the Nd isotope composition, we have analysed the Nd isotopic composition of the various horizons includin g living plants and humus of two profiles of weathered till (typic haplocry ods) in northern Sweden. As much as between 65.6 and 75.3% of the Sm and Nd in the <0.2 mm fraction has been lost from the E-horizon, and between 32.5 and 54.7% from the B-horizon. Nd has been lost to a slightly greater exten t than Sm. The two C-horizon samples have epsilon(Nd(0)) values of -22.1 an d -23.2. Corresponding E-horizon values an -18.1 and -20.2. The B-horizon v alues are intermediate between the values of the E and C horizons. It is co ncluded that the weathering leads to a change in the Sm/Nd ratio resulting in a change of the Sm-Nd isotope composition. The plant and humus samples d eviate even more from the unweathered till. For one station the results cou ld be interpreted as if the Sm and Nd taken up by the plants had similar is otope characteristics as the amounts of these elements released by weatheri ng in the E-horizon. For the other station it is probable that the Nd isoto pe composition of the organic samples is dominated by Nd released by till w eathering which, however, is mixed with another Nd-source, possibly an airb orne component. The explanation to the change of isotope compostion in the till is that a larger proportion of the Nd released by weathering is releas ed from minerals with a lower Sm/Nd ratio than the bulk soil, compared with the amount released from minerals with a higher Sm/Nd ratio. Although the various REE-carrying minerals had the same initial Nd isotopic composition, 1.8-1.9 Ga of decay of Sm-147 to Nd-143 has resulted in a higher present N d-143/Nd-144 ratio in the minerals with a higher Sm/Nd ratio. Copyright (C) 2000 Elsevier Science Ltd.