The use of chromium(III) salts is under review by global industries. One of
the options for better management of chromium is through recovery and reus
e. Batch type processes for the recovery of chromium and subsequent use in
tanning has already gained importance in the tanning industry. Here we desc
ribe a novel semi-continuous method for the recovery of chromium(III) from
tannery wastewaters containing the metal ion. In this system, sodium carbon
ate is used as the alkali to precipitate chromium(III) as chromium(III) hyd
roxide, instead of magnesium oxide, which is preferred for batch type syste
ms. The hydrostatic pressure build-up and turbulence within the reactor is
modulated to achieve online separation of chromium(III) hydroxide. Under st
eady state conditions, the inflow into the reactor is matched by the outflo
w. The outflow from the reactor can be discharged without causing ground-wa
ter hardness.