The recent development of techniques for laser-driven shock compression of
hydrogen has opened the door to the experimental determination of its behav
ior under conditions characteristic of stellar and planetary interiors. The
new data probe the equation of state (EOS) of dense hydrogen in the comple
x regime of pressure ionization. The structure and evolution of dense astro
physical bodies depend on whether the pressure ionization of hydrogen occur
s continuously or through a "plasma phase transition" (PPT) between a molec
ular state and a plasma state. For the first time, the new experiments cons
train predictions for the PPT. We show here that the EOS model developed by
Saumon and Chabrier can successfully account for the data, and we propose
an experiment that should provide a definitive test of the predicted PPT of
hydrogen. The usefulness of the chemical picture for computing astrophysic
al EOS and in modeling pressure ionization is discussed.