High-spin low-spin transition

Authors
Grunsteudel, H Paulsen, H Winkler, H Trautwein, AX Toftlund, H
Citation
H. Grunsteudel et al., High-spin low-spin transition, HYPER INTER, 123(1-8), 1999, pp. 841-846
Citations number
21
Categorie Soggetti
Physics
Journal title
HYPERFINE INTERACTIONS
ISSN journal
03043843 → ACNP
Volume
123
Issue
1-8
Year of publication
1999
Pages
841 - 846
Database
ISI
SICI code
0304-3843(1999)123:1-8<841:HLT>2.0.ZU;2-8
Abstract
Temperature dependent nuclear inelastic-scattering (NIS) of synchrotron rad iation was applied to investigate both spin states of the spin-crossover co mplex [Fe(tpa)(NCS)(2)] (tpa = tris(2-pyridylmethyl)amine). A remarkable in crease of the iron-ligand bond stretching upon spin crossover has unambiguo usly been identified by comparing the measured NIS spectra with theoretical simulations based on density-functional calculations.