By tailoring Zr/Ti ratio in Pb(Zr,Ti)O-3 from 45/55 to 75/25, functionally
graded PZT thin films were prepared by metal organic decomposition (MOD) te
chnique. P-E hysteresis loops were measured, and polarization was found to
shift up or down depending on the direction of the composition gradients of
the PZT. This polarization offset was modeled using Poisson's equation in
one dimension. Switching charge was also found to be compositional gradient
direction dependent.