In this article, we report on the observation of the formation of negativel
y charged ions upon reflection from an aluminum-nitride surface. Positive H
-2 and O-2 ions are scattered at small angles of incidence off a single-cry
stal surface. Charge exchange at the surface yields neutral particles and n
egative ions in the reflected particle flux. The negative ion fractions are
about 15% and 1% for oxygen and hydrogen, respectively. The particle refle
ction probability is only 2%, which is attributed to the roughness of the s
urface. (C) 2000 American Institute of Physics. [S0021-8979(00)08805-8].